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On the Ice => The Pro Shop => Topic started by: Bill_S on July 31, 2017, 05:45:40 PM

Title: Rust removal from blades - experiments
Post by: Bill_S on July 31, 2017, 05:45:40 PM
Because of a recent thread, I became curious about which common household product could do the best job removing rust. I tried three non-abrasive products - Lime-A-Way, Bar Keepers Friend, and Naval Jelly. There was one clear winner - Bar Keeper's Friend.

(http://www.afterness.com/skating/images/skate_blade_rust-43-600px.jpg)

Bar Keeper's Friend is a non-abrasive powder meant for cleaning metal cookware. The active ingredient is oxalic acid. This acid is naturally present in bitter greens, i.e. rhubarb contains it.

The other two products are in liquid form, and are more dangerous to handle. Lime-A-Way contains sulfamic acid, and Naval Jelly contains phosphoric acid as active ingredients.


The Experiments

I started with an old pair of skates stored in my basement. The rust was a bit more than just surface rust, and had slightly pitted the hollows of both blades. The rust followed the pattern of the hard guard in which they were stored, and areas of contact rusted. Here's a shot of one of the blades used for testing before application of any treatment...

(http://www.afterness.com/skating/images/skate_blade_rust-13-600px.jpg)
One of the untreated blades showing rust

(sorry for the slightly fuzzy picture - this was a rush job!)

The Naval Jelly is a product for removing rust in marine and automotive uses. I dipped a Q-Tip into the thick liquid, and applied it directly to a couple of the rust areas. After application, I waited 5 or so minutes per instructions, then wiped it off. While it was an improvement, it didn't remove some of the rust, but more worrisome, it left a dark stain where it had been in contact with the metal.

(http://www.afterness.com/skating/images/skate_blade_rust-5-600px.jpg)
Naval Jelly treatment.

Next I tried the Lime-A-Way. I wetted the Q-Tip with it, and rubbed for about a minute over an area of rust. The rust clearly was transferred to the Q-Tip, but the result still wasn't as good as the Bar Keepers Friend described next.

(http://www.afterness.com/skating/images/skate_blade_rust-16-600px.jpg)
Lime-A-Way treatment

The last product, Bar Keeper's Friend was applied using a damp Q-Tip to which the powder was applied. I did about a minute of vigorous rubbing on a couple of rust spots. Even the spot that remained after using Lime-A-Way was subsequently improved by using Bar Keeper's Friend. It took care of fresh spots quickly too, and left the best finish.

(http://www.afterness.com/skating/images/skate_blade_rust-19-600px.jpg)
Bar Keeper's Friend treatment

By feel, it left the smoothest surface. I had feared some minor pitting would remain, and it did, but the BKF treatment left the smoothest surface of the three products tested.

It was a clear win for Bar Keepers Friend.

Of course a good sharpening would beat any of these products, but there are times when this may come in handy.
Title: Re: Rust removal from blades - experiments
Post by: AgnesNitt on July 31, 2017, 06:44:16 PM
I use a gummi stone. I suspect a jeweler's emery would work as well.

Title: Re: Rust removal from blades - experiments
Post by: Query on August 02, 2017, 12:32:39 AM
BTW, Bar Keeper's friend is abrasive.

https://www.barkeepersfriend.com/cleaning-products/cleanser-polish says

Quote
Ingredients

mineral abrasive, oxalic acid, surfactant, water-softening agent

Interestingly enough it only says to use it on stainless steel. It doesn't explicitly mention non-stainless steel.

I have used it on stainless steel cookware. Much better than Ajax and Comet, because they have a larger grain size, which leaves obvious scratches, that bacteria could get into. It's great stuff for removing stains and slight burns from stainless steel from pots and pans.

Be careful not to rub or scrape at the edges, if you can - I think anything like this could dull them a bit.

Did you try vinegar? As a mild acid, it does react with rust, and remove the oxygen, to an extent. But, because it isn't an abrasive, it may not leave a smooth surface, so at least on cookware, I like Bar Keeper's friend better.
Title: Re: Rust removal from blades - experiments
Post by: fsk8r on August 02, 2017, 12:53:40 AM
Glad to hear Barkeepers friend works. I'm currently trying to hunt for some.
I've had a brand new set of blades which have gone very rusty after only a couple of hours skating and then some long storage.

My own experiments have been with citric acid and cream of tartar (tartaric acid for the chemists). This mix has taken a lot of rust off, but not finished the job. Adding a little hydrogen peroxide has also helped the rust removal.

Vinegar would probably work, but the barkeepers friend has a stronger acid so is likely to work better.
I'm currently debating using some limescale remover as that should be a strong acid, but I'm not sure about it's concentration.

Title: Re: Rust removal from blades - experiments
Post by: Query on August 02, 2017, 12:58:42 AM
Try Walmart, or many grocery and hardware places. It's very common.

The manufacturer website has a "where to buy" link.
Title: Re: Rust removal from blades - experiments
Post by: Bill_S on August 02, 2017, 08:43:49 AM
Query: Thanks for pointing out that Bar Keepers Friend contains mild abrasive. The term "polish" on the front of the can hints at that. It is a very mild abrasive as you describe, and I use it everyday on my cookware without abrasive scratches forming. It's good stuff.

Going further, I remembered that some of the woodworking forums that I frequent discuss rehabbing old, rusty tools. Some of them are career restorers who bring back to life some really rusty basket-cases.

They praise liquid Evapo-Rust as a good overnight soaking treatment to remove rust. The MDS sheet doesn't reveal the active ingredient (must not be toxic - good!). Further searching found that it could be  ethylenediaminetetraacetate or EDTA.

I wish that I had some Evapo-Rust on hand to try. It sounds promising, but because a long soak is suggested, either the blades would have to sit in a shallow dish, or removed from the boots for treatment. Either is easy enough to do though.
Title: Re: Rust removal from blades - experiments
Post by: sampaguita on August 02, 2017, 09:05:03 AM
I used petroleum jelly with a Scotch Brite scouring pad to remove a very thick layer of rust from my old skates. It worked rather well, but I had to be careful not to dull the actual edges. It was manageable.

Using oxalic acid is interesting. Would you know what concentration BKF uses?
Title: Re: Rust removal from blades - experiments
Post by: Bill_S on August 02, 2017, 09:37:41 AM
The MDS sheet lists the Oxalic acid at 7.5 to 9.5% by weight.

There are two other ingredients listed, Feldspar (% is proprietary, and I suspect that this is the mild polishing agent), and Linear Sodium Dodecyl Benzene Sulfonate (DDBSA) -  essentially detergent.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 02, 2017, 09:47:07 AM
If there's moderate to heavy rust on skate blades, you'll want to remove the rust before you have them resharpened so the rust doesn't foul the grinding wheel; and a clean, uniform initial surface will make it easier to achieve uniform edges.  A careful sharpener will probably remove the rust first anyway, but he may charge you extra.  Since you'll probably want them resharpened, however, I don't see the need to be super-meticulous about abrasives in the rust remover, as long as they are not too coarse, and potential dulling of the edges. 

If it's just superficial staining, then, as Bill mentioned, it'll probably be gone in the course of a session or so anyway, without any deliberate rust removal action.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 02, 2017, 10:55:55 AM
I used petroleum jelly with a Scotch Brite scouring pad to remove a very thick layer of rust from my old skates. It worked rather well, but I had to be careful not to dull the actual edges. It was manageable.
I tend to stay away from acid-based rust removers, and use a method similar to yours for general purpose rust removal.  Except I use Liquid Wrench Penetrating Oil, instead of petroleum jelly, with Scotch Brite.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 02, 2017, 10:56:42 AM
//entered in error; can't delete//
Title: Re: Rust removal from blades - experiments
Post by: lutefisk on August 02, 2017, 11:51:38 AM
Query: Thanks for pointing out that Bar Keepers Friend contains mild abrasive. The term "polish" on the front of the can hints at that. It is a very mild abrasive as you describe, and I use it everyday on my cookware without abrasive scratches forming. It's good stuff.

Going further, I remembered that some of the woodworking forums that I frequent discuss rehabbing old, rusty tools. Some of them are career restorers who bring back to life some really rusty basket-cases.

They praise liquid Evapo-Rust as a good overnight soaking treatment to remove rust. The MDS sheet doesn't reveal the active ingredient (must not be toxic - good!). Further searching found that it could be  ethylenediaminetetraacetate or EDTA.

I wish that I had some Evapo-Rust on hand to try. It sounds promising, but because a long soak is suggested, either the blades would have to sit in a shallow dish, or removed from the boots for treatment. Either is easy enough to do though.


I've bought Evapo-rust at Auto Zone stores.  Some stock it, others don't.  One can check with the company's website to find a place to purchase the stuff.  In my experience, Evapo-rust works well on ferrous items that you can submerge in a plastic tuperware style tray of the stuff and lock a cover on to limit evaporation.  Be aware that the process tends to make the rusty areas change color.  Since Evapo-rust works via chelation, it removes a tiny bit of iron from the rusted (iron oxide) areas rather than converting the iron oxide to iron phosphate as is the case of most other products.  So at bit of polishing with a mild abrasive might be in order apres treatment.  (Aside:  toothpaste contains a very mild abrasive).   Also, after treatment with Evapo-rust and the polish of choice, one should probably take steps to prevent further rusting--which could start as soon as the Evapo-rust is washed away.  In most cases of rust abatement this means painting the metal object with a protective coating.  In the case of skate blades this is probably not the most desirable option, although there may be a clear coat that could be applied.  In theory Evapo-rust should work on skate blades.  I've used it to de-rust small auto parts and rusty tools which were small enough to submerge for a couple days in a plastic tub.  It works well.
Title: Re: Rust removal from blades - experiments
Post by: Kaitsu on April 15, 2022, 12:56:57 PM
Bill, have you seen this?

https://www.barkeepersfriend.com/how-to-clean-ice-skating-blades/
Title: Re: Rust removal from blades - experiments
Post by: supersharp on April 15, 2022, 01:45:54 PM
That's great!  Bill has found his new retirement hobby...product endorsements!
Title: Re: Rust removal from blades - experiments
Post by: Bill_S on April 15, 2022, 02:32:41 PM
Hooray, it's my 15 minutes of fame!  ;D  ;D
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on April 15, 2022, 02:51:02 PM
Bill, if the company were really decent, they would send you a complimentary case!  I'm surprised though that they consider the rusty/corroded/tarnished ice skate market to be big enough to warrant a dedicated article.
Title: Re: Rust removal from blades - experiments
Post by: Isk8NYC on April 15, 2022, 11:12:05 PM
Bill, have you seen this?

https://www.barkeepersfriend.com/how-to-clean-ice-skating-blades/

Bravo, Bill deserves a lifetime supply for endorsing the product!  I've always thought that the tech crew here could write articles about skates and blades to make some $$$!

I'm not really a "numbers person," but I do look at the forum stats occasionally.  It's amazing how random web pages linking to SF leads to big jumps in the number of page views.  Agnes Nitt once posted something on her blog that linked to us and the numbers soared for a few days.
Title: Re: Rust removal from blades - experiments
Post by: Kaitsu on July 24, 2022, 04:55:26 AM
Another way to remove rust from the blades... https://youtu.be/aX_Iv-k4Ak4
Title: Re: Rust removal from blades - experiments
Post by: Query on July 25, 2022, 01:53:58 PM
Another way to remove rust from the blades... https://youtu.be/aX_Iv-k4Ak4

There a a significant number of scratches on the side of the blade when the person is done. So maybe it is a coarser abrasive than Bar Keeper Friend?

The person abrades the whole side of the blade. So they are gradually removing the chrome (?) plating that helps prevent future rust. Those scratches tell me they are removing a fair bit of metal. Perhaps it would be better, to only abrade the bottom "chrome relief region", where is no plating?

I wonder if using a coarse abrasive like that could alter the thickness profile of the bottom of the blade in a non-uniform manner, sufficiently to affect skating.

On the plus side, if you wanted to play with parabolic or tapered side honing on currently parallel sided blades, it might be a fairly fast way to create it.

Also, I have a somewhat rusted pot (a building contractor where I used to live left water in it overnight without asking), that ordinary treatments can't fix. Maybe the coarser abrasive (followed by Bar Keeper Friend to make it smooth again) would do the job - but so might sandpaper.

Of course, I'm sure we all agree that rust prevention is better than rust removal. But prevention is a separate topic, which has been covered many times in these forums.
Title: Re: Rust removal from blades - experiments
Post by: supersharp on July 25, 2022, 07:04:27 PM
There a a significant number of scratches on the side of the blade when the person is done. So maybe it is a coarser abrasive than Bar Keeper Friend?

The person abrades the whole side of the blade. So they are gradually removing the chrome (?) plating that helps prevent future rust. Those scratches tell me they are removing a fair bit of metal. Perhaps it would be better, to only abrade the bottom "chrome relief region", where is no plating?


I disagree about the scratches--if you look at the view before and after polishing off the rust, the same scratches are present on the blade before it is given the rust removal treatment. 
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on July 26, 2022, 08:51:18 AM
I wonder if using a coarse abrasive like that could alter the thickness profile of the bottom of the blade in a non-uniform manner, sufficiently to affect skating.

On the plus side, if you wanted to play with parabolic or tapered side honing on currently parallel sided blades, it might be a fairly fast way to create it.

The product in the video is called Universal Stone.  Strange that the video didn't explicitly call it out.  But I did a freeze frame when the container was shown.  I couldn't find details of its composition; but it doesn't appear to be an intentionally coarse abrasive. 

But why use this product to modify the blade thickness profile in your proposed scheme?  Just as you can buy abrasive papers and whetstones with different degrees of graded coarseness, you can also buy loose abrasive powders with different degrees of graded coarseness.  Mix them with the base of your choice to create a slurry or paste.

The $60K question:  How do you plan to control the blade thickness profile in your proposed scheme?
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on July 26, 2022, 09:02:33 AM
I disagree about the scratches--if you look at the view before and after polishing off the rust, the same scratches are present on the blade before it is given the rust removal treatment.
Yeah. The blade looked like it was mildly, rather than heavily, rusted.  From the timestamps on the video, it took nearly 90 sec of vigorous scrubbing (not including the wiping after the scrubbing) to get rid of the rust.  So the abrasive couldn't have been too coarse.
Title: Re: Rust removal from blades - experiments
Post by: Query on July 26, 2022, 12:50:20 PM
I disagree about the scratches--if you look at the view before and after polishing off the rust, the same scratches are present on the blade before it is given the rust removal treatment.

Oh - I did the wrong freeze frames. Some of the scratches appear at some angles, but not others. So this is another case where tiny, tiny changes in lighting and viewing angle can radically change what you see... What a nuisance.

Quote
>tstop4me wrote
The $60K question:  How do you plan to control the blade thickness profile in your proposed scheme?

I don't plan to do this. I don't personally believe there is much difference (at my low skating level) between parallel and other side honings - except possibly dovetail cut, which would be really difficult to produce this way, but which alters the included angle of the edge. Though there are people who claim the difference between different forms of side honing is significant.

At my skating level, I probably couldn't test the effects in a meaningful way, because the precise way I skate isn't consistent enough to perform well enough controlled experiments to eliminate placebo effects, or my personal prejudices about whether the difference is significant. E.g., some people have claimed that some forms of side honing create longer and/or faster glides - but I'm not good enough to keep my how deep my edge is perfectly consistent between two trials - and the ice might change roughness or temperature in the intervening time. Again, some people have claimed that some forms of side honing make it easier to turn and or land a jump - but once again my technique isn't consistent enough to perform well controlled experiments. I suspect the time I would waste on the experiment would be better spent practicing skating, or doing something else fun.

I have always found it interesting that some people have claimed you can skate faster if the blade is tapered thicker up front (sort of like a rain drop), and some people have claimed it is better if it is thinner up front. That is one of the reasons I have been skeptical of claims about side honing.

Likewise, one very experienced coach told me that parabolic side honing helped her daughter land jumps. But it was the opposite for her. I wondered if the other poorly controlled factors in blade shape might have produced that differences in performance.

If one did want to try side honing, I suppose one could take a micrometer and measure the thickness at many points, and iteratively try to achieve a given thickness profile with the abrasive slurry. I admit that that would be slow and clumsy, but it wouldn't require any tools I don't have. But maybe some form of sandpaper would be better - because one could apply it to a very thin layer at the bottom of the blade, and abandon that layer if one didn't like it.

At a guess, there are probably machine shop tools which can do side honing faster and perhaps better. I don't know what commercial blade makers use. But good machine shop tools are very expensive. Not something your average skater is likely to buy.

Maybe side honing could be imposed by some of you with powered sharpening machines - sort of a machine shop tool, but one that several of you have already bought - if you made or bought a guide - somewhat like a rocker bar, but of course with much less curvature. I'm not experienced enough with such machines to how that would work, and how you would mount the skate blade at the correct angle to use it without the rest of the skate or blade getting in the way, but perhaps one of you could figure out a way.

I wonder if this abrasive is significantly different in application or effect from Bar Keepers Friend. 

I haven't had much if any call to remove rust from the particular stainless steel alloy my current blades are made from, because I try to take good care of them. Except when I had flood damage - but there was so much rust on those blades that nothing could have saved them.
Title: Re: Rust removal from blades - experiments
Post by: supersharp on July 26, 2022, 05:12:45 PM
Our rink opens in a few days, so my guess is I will start to see a pile of blades that have varying degrees of rust on them. 
 
"I have no idea how this happened, she is always so careful" will be the comment from the parents.  What I have observed is that on the last day of skating, there is a lot of social interaction happening as people take off their skates and realize they won't see some of their skating friends for months, and there is less attention paid to the blades.  Same thing happens after a show or a test session.  Most skaters do not go home and coat their blades with vaseline or wax to protect them during the months off the ice.  Some don't even take them out of their bag, which is part of why the boots stink (that could be a whole different thread--ways to overcome boot stench!). 

I'm always glad to see more tested options for relatively quick and successful rust removal, particularly because I can't always find Bar Keeper's Friend.  Some stores here have BonAmi, which is a very different formulation than BKF, but maybe is worth a try as a comparison product.
Title: Re: Rust removal from blades - experiments
Post by: Kaitsu on August 05, 2022, 01:07:50 PM
The pink stuff paste seems to work also for rust when used in same way as Universal stone in the video, but it seems to be less abrasive.

Query,
I have challenge for you. Buy somewhere Universal Stone and try to polish the chrome layer away from some of your worn-out blades. When we hear you next time, we know that you have managed to remove chrome layer. It should not take so long if Universal Stone is so abrasive as you believe. When you are retired scientist, you have all day long for polishing.  :)

Brand was not mentioned in the video as intention was not promote any certain brand which is not possible easily available locally. Point was highlight that the clay is "secret" and you can try to find similar product from the local super market. Clay is used example in many washing machines washing powders, so even regular washing powder could work as well. Clay abrasive properties  is the reason why such a washing powders destroys (in long term use) also your washing machine water pump plastic bearing housing (which is water lubricated) and it gets noisy. Clay stones are used also clean / polish cars painting and in many other places. You can find plenty of information about the clay by Googling or from the Youtube.
Title: Re: Rust removal from blades - experiments
Post by: Query on August 08, 2022, 03:14:45 PM
Why would I want to do that? A waste of time and money.

If this description

https://www.walmart.com/ip/Universal-Stone-The-All-Purpose-Stone-That-Foams-Cleans-Polishes-And-Protects-Sponge-Included/983882969

is correct, Universal stone is "non-abrasive". If that's perfectly true, I could spend forever at what you propose.

At first glance, that description sounds a little too good to be true. How does something remove lime and hard water deposits without being acidic, or at least containing water? How can polishing clay (which I assume to be fine grained worn rock grains, such as quartz) be biodegradable, or perfectly non-abrasive?
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 09, 2022, 04:55:55 AM
At first glance, that description sounds a little too good to be true. How does something remove lime and hard water deposits without being acidic, or at least containing water?

<<Emphasis Added>>  If you read the Product Details you cited, you will find the following application instructions:

The cleaner is packaged as a dry, compressed powder and has an indefinite shelf life. .... Wipe a damp sponge across the stone a few times. Squeeze the sponge to produce foam and begin cleaning. Rinse the cleaned surface with water or polish with a damp cloth. Let the stone dry after use, then close the container.  <<Emphasis Added>>
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 09, 2022, 09:35:48 AM
How can polishing clay (which I assume to be fine grained worn rock grains, such as quartz) be biodegradable, or perfectly non-abrasive?

<<Emphasis Added>>  Again, if you read the Product Details you cited, they never state the product is "perfectly non-abrasive" (whatever that means; see further discussion below), only non-abrasive:

"The cleaner is non-abrasive and is safe for use on silverplate or heirloom silver."

And what constitutes "non-abrasive" will depend on the surface the cleaner is applied to, the duration of scrubbing, and the resolution of the thickness removed, among other factors (e.g., assuming the abrasiveness of the applicator is not significant).

With respect to compatible surfaces, the Product Details state:

"Use it on stainless steel, silver, gold, copper, brass, aluminium or chrome; on tiles, marble, granite, floors, countertops and backsplashes, sinks, tubs, toilets and taps, stove tops, windows and cabinets; on glass, crystal, enamel, plastic, acrylic, painted wood, ceramics or jewelry. The cleaner is non-abrasive and is safe for use on silverplate or heirloom silver.
....
* Safe for: Stainless steel, silver, gold, copper, brass, aluminum, chrome, fine crystal, marble, granite, enamel, ceramic, acrylic, vinyl, wood, jewelry, shoes and more ..."

With respect to duration of cleaning, no details are given.  But for household cleaning products of this sort, we typically think of scrubbing times on the order of seconds or minutes (maybe max of 10 minutes or so), and not scrubbing times on the order of hours, days, weeks, months, years, decades, or centuries.

With respect to resolution of thickness removed, there are instruments that, for specific materials under specific conditions, can detect the removal of a single atomic layer.  But for household cleaners, we typically consider them to be non-abrasive if they don't cause visible (to the eye without the assistance of instruments)  scratches (as in the famous Bon Ami slogan).
Title: Re: Rust removal from blades - experiments
Post by: Kaitsu on August 09, 2022, 01:17:58 PM
Why would I want to do that? A waste of time and money.

a) Because it was you whom said following...
The person abrades the whole side of the blade. So they are gradually removing the chrome (?) plating that helps prevent future rust. Those scratches tell me they are removing a fair bit of metal. Perhaps it would be better, to only abrade the bottom "chrome relief region", where is no plating?

I wonder if using a coarse abrasive like that could alter the thickness profile of the bottom of the blade in a non-uniform manner, sufficiently to affect skating.

You could be even ones a man and proof that you was right, by trying to polish chrome layer away with Universal Stone.

b) The time you are busy on other activities might be luxury time for others.
Title: Re: Rust removal from blades - experiments
Post by: Query on August 11, 2022, 10:56:07 AM
And what constitutes "non-abrasive" will depend on the surface the cleaner is applied to, the duration of scrubbing, and the resolution of the thickness removed, among other factors (e.g., assuming the abrasiveness of the applicator is not significant)...

With respect to duration of cleaning, no details are given.  But for household cleaning products of this sort, we typically think of scrubbing times on the order of seconds or minutes (maybe max of 10 minutes or so), and not scrubbing times on the order of hours, days, weeks, months, years, decades, or centuries.

With respect to resolution of thickness removed, there are instruments that, for specific materials under specific conditions, can detect the removal of a single atomic layer.  But for household cleaners, we typically consider them to be non-abrasive if they don't cause visible (to the eye without the assistance of instruments)  scratches (as in the famous Bon Ami slogan).

Where did you find this definition of "nonabrasive"?

I tried without success to find a US legal definition of the term online. What I did find is that some US laws refer to Merriam-Webster's dictionary for terms not defined within the law.

www.merriam-webster.com defines "<a href=https://www.merriam-webster.com/dictionary/nonabrasive>nonabrasive</a> (as an adjective) as "not abrasive", It defines "<a href=https://www.merriam-webster.com/dictionary/abrasive>abrasive</a> as "causing damage, wear, or removal of surface material by grinding or rubbing : tending to abrade"

At least in my personal experience water alone will not remove lime or other significant hard water deposits, if you use the same hard tap water that left the deposits in the first place. Even if you soften it, it would take virtually forever, unless you are talking about surfaces like smooth glass which it barely adheres. Have you ever tried to remove lime from a fiberglass bathroom shower stall? You need acid (preferably strong acid solution like Lime Away or CLR), combined with with a lot of scrubbing using strong abrasives (like a hard steel brush). Some people claim that vinegar + baking soda + scrubbing is enough, but I couldn't make significant headway that way on a stall that had a few years worth of lime deposit.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 12, 2022, 06:59:29 AM
At least in my personal experience water alone will not remove lime or other significant hard water deposits, if you use the same hard tap water that left the deposits in the first place. Even if you soften it, it would take virtually forever, unless you are talking about surfaces like smooth glass which it barely adheres. Have you ever tried to remove lime from a fiberglass bathroom shower stall? You need acid (preferably strong acid solution like Lime Away or CLR), combined with with a lot of scrubbing using strong abrasives (like a hard steel brush). Some people claim that vinegar + baking soda + scrubbing is enough, but I couldn't make significant headway that way on a stall that had a few years worth of lime deposit.

<<Emphasis added>>  Who (besides you here) is talking about "water alone"?  I was merely responding to your previous post:

At first glance, that description sounds a little too good to be true. How does something remove lime and hard water deposits without being acidic, or at least containing water?

<<Emphasis added>>  I'm not commenting on whether what you've posted is accurate or not.  I'm only saying that if you read the instructions (that you cited) for Universal Stone, you will note that water is added (via a damp sponge) to the Universal Stone product, which is supplied as a dry powder.  So the cleaning is done by a combination of water and Universal Stone product; therefore, the final cleaning agent (a) is not water alone and (b) does at least contain water.  Whether it works or not, I don't know; I've never used the stuff.  But it does satisfy one of the criteria that you have stipulated.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 12, 2022, 08:27:10 AM
Where did you find this definition of "nonabrasive"?

I tried without success to find a US legal definition of the term online. What I did find is that some US laws refer to Merriam-Webster's dictionary for terms not defined within the law.

www.merriam-webster.com defines "<a href=https://www.merriam-webster.com/dictionary/nonabrasive>nonabrasive</a> (as an adjective) as "not abrasive", It defines "<a href=https://www.merriam-webster.com/dictionary/abrasive>abrasive</a> as "causing damage, wear, or removal of surface material by grinding or rubbing : tending to abrade"

Let’s rewind to your post that I was responding to:

How can polishing clay (which I assume to be fine grained worn rock grains, such as quartz) be biodegradable, or perfectly non-abrasive?

Which I interpret to mean:  “If it contains polishing clay, it can’t be non-abrasive.”

To which, I replied:

And what constitutes "non-abrasive" will depend on the surface the cleaner is applied to, the duration of scrubbing, and the resolution of the thickness removed, among other factors (e.g., assuming the abrasiveness of the applicator is not significant).

I’ll expand upon my previous response.  In order to determine whether or not a cleaner is “non-abrasive”, you first need to specify the criteria for “non-abrasive”.  One way to do this would be to specify a maximum removal rate (thickness removed/scrubbing time) under specified conditions.  If I specify the maximum removal rate to be sufficiently low, then Universal Stone will fail the test for “non-abrasive”.  Of course, I can specify the maximum removal rate to be so low such that virtually all cleaners will fail the test; e.g., I set the maximum removal rate to 1 nanometer/hr.  On the flip side, if I set the maximum removal rate sufficiently high, then Universal Stone will pass the test.  As far as I know, there is no such specification for “non-abrasive”.

But with respect to consumer cleaners, what are we typically interested in?  If I’m buying a non-abrasive auto cleaner, I want a cleaner that won’t scratch the paint.  If I’m buying a non-abrasive eyeglass cleaner, I want a cleaner that won’t scratch the lenses.   ...  So are there plausible criteria under which Universal Stone could be declared “non-abrasive”?  In the absence of any government regulations, and in the absence of citations to any industry standards, yes.  So, you can’t simply dismiss Universal Stone’s claim to be non-abrasive merely on the basis of “If it contains polishing clay, it can’t be non-abrasive.”
Title: Re: Rust removal from blades - experiments
Post by: Query on August 12, 2022, 03:40:11 PM
OK. You are right. If there are no clear standards, an advertiser can apply whatever definition they want.

So... Let's use that no scratches to the naked eye definition. A "nonabrasive" skate sharpener, would be great, right?


I have similar problems with a lot of ads.

"Design without compromise." 

"99 and 44/100% pure soap."

"The leading [fill in any product category].

Electric heaters that are said to be much more efficient than other brands.

Electric motors whose horsepower is much greater than nominal input amps*volts/746.

Kitchen appliances touted to the public as what restaurants use, but not meeting the cleanability standards that restaurants must follow, or not UL listed as safe for home use, and/or less heavy duty than commercial models, and/or that trip modern home AFCIs.

Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 13, 2022, 08:30:41 AM
OK. You are right. If there are no clear standards, an advertiser can apply whatever definition they want.
It's a more fundamental issue than that.  The issue arises when you try to categorize a property of a material into a simple binary classification "X/non-X"  when in fact X has a continuous or quasi-continuous range of values from XMIN to XMAX:  "electrically conducting/electrically non-conducting (electrically insulating)", "optically transparent/optically non-transparent (optically opaque)" , "toxic/non-toxic", ....
Title: Re: Rust removal from blades - experiments
Post by: Query on August 13, 2022, 07:54:15 PM
I guess if one wanted to know how much if any chrome plating was removed by a rust removal process, one might be able to use a micrometer. Of course, you might need to make alignment marks, so you would measure in exactly the same place, and one would need to make sure one wasn't testing in a rusted spot, where removal was desirable.

As far as you know (please don't test this on your expensive blades), would Universal Stone remove less chrome than Bar Keepers Friend, and/or less of the edge?

Based on this ingredient list (https://homecleaningfamily.com/bar-keepers-friend-ingredients), it looks like the main abrasive in Bar Keeper's friend is feldspar. If I am correct in guessing (and it really just is a guess) that the main abrasive in Universal stone is quartz (assuming the clay is mostly made from naturally polished sand, which is mostly quartz), this page (https://www.oakton.edu/user/4/billtong/eas100lab/hardness.htm) says quartz is harder (which in this case means scratch resistant) than feldspar, and typical steels lie in between the two in hardness, so in that sense Bar Keepers Friend might be less likely to scratch steel.

But I'm not sure that argument is valid. For one thing, there might be a huge difference in the hardness of steels.

Plus I'm not sure how to find a similar hardness (scratch resistance) rating for chrome plating. I assume it is less hard than steel, otherwise there would be no "chrome relief" zone.


On a separate note, I think the main reason people need to remove rust from reasonably well treated blades is that they aren't using stainless steel blades. Given reasonable treatment, it isn't nearly as much a problem on stainless blades.

Can you explain in very simple terms the probable reason why MK and JW don't use stainless steel in most of their reasonably high end figure skating blades? You have said before that stainless is harder to sharpen (specifically, that some grinding wheels don't sharpen stainless well) - is it also harder to cut, given that they now use laser cutters? (Note: melting points of steels (https://shipbuildingknowledge.wordpress.com/2019/01/05/melting-point-of-carbon-steel-stainless-steel) are in the same approximate range) Or to temper, and re-harden? Or is it harder to weld? Or, since they say what they use is a "spring steel", does it have better mechanical properties than stainless? Or is it economic: maybe they want the blades to corrode fast, so they are replaced more often?

At one point Katisu pointed out that magnetism could make it harder to sharpen blades, because the filings stick to the blade, and this site (https://jfheattreatinginc.com/2022/05/the-difference-between-clean-steel-and-stainless-steel) claims that stainless is magnetic, whereas "clean steel" is not. Would that significantly affect manufacturing ease?

Their pricey Phoenix (https://www.johnwilsonskates.com/phoenix) blades do use 420 stainless, so they must not think it too bad.

They have been in business long enough that I assume they have thought the matter through. I would think there must be a good reason, or combination of reasons.

Either that, or they think customers want to get what they have always gotten.
Title: Re: Rust removal from blades - experiments
Post by: tstop4me on August 14, 2022, 07:21:42 AM
I guess if one wanted to know how much if any chrome plating was removed by a rust removal process, one might be able to use a micrometer. Of course, you might need to make alignment marks, so you would measure in exactly the same place, and one would need to make sure one wasn't testing in a rusted spot, where removal was desirable.

As far as you know (please don't test this on your expensive blades), would Universal Stone remove less chrome than Bar Keepers Friend, and/or less of the edge?

During one phase of my R&D career, I did extensive studies of polishing of specific semiconductor wafers by specialized techniques.  So I'm well aware of the methods and equipment needed for such studies.  Since removal rates of chrome by rust removers appear to be of particular interest to you, I'll leave the work to you.  As for me, I currently have Paramount blades with 440C stainless steel runners; no chrome plate; rust is not an issue.  When I need to remove rust from plain carbon steel blades for friends of mine, I use the method I posted earlier in this thread:

I tend to stay away from acid-based rust removers, and use a method similar to yours for general purpose rust removal.  Except I use Liquid Wrench Penetrating Oil, instead of petroleum jelly, with Scotch Brite.


On a separate note, I think the main reason people need to remove rust from reasonably well treated blades is that they aren't using stainless steel blades. Given reasonable treatment, it isn't nearly as much a problem on stainless blades.

Can you explain in very simple terms the probable reason why MK and JW don't use stainless steel in most of their reasonably high end figure skating blades? You have said before that stainless is harder to sharpen (specifically, that some grinding wheels don't sharpen stainless well) - is it also harder to cut, given that they now use laser cutters? (Note: melting points of steels (https://shipbuildingknowledge.wordpress.com/2019/01/05/melting-point-of-carbon-steel-stainless-steel) are in the same approximate range) Or to temper, and re-harden? Or is it harder to weld? Or, since they say what they use is a "spring steel", does it have better mechanical properties than stainless? Or is it economic: maybe they want the blades to corrode fast, so they are replaced more often?

At one point Katisu pointed out that magnetism could make it harder to sharpen blades, because the filings stick to the blade, and this site (https://jfheattreatinginc.com/2022/05/the-difference-between-clean-steel-and-stainless-steel) claims that stainless is magnetic, whereas "clean steel" is not. Would that significantly affect manufacturing ease?

Their pricey Phoenix (https://www.johnwilsonskates.com/phoenix) blades do use 420 stainless, so they must not think it too bad.

They have been in business long enough that I assume they have thought the matter through. I would think there must be a good reason, or combination of reasons.

Either that, or they think customers want to get what they have always gotten.

* You asked the same question before in another thread:

If you did call - I would love to know if there is a good reason MK/JW uses non-stainless steels, as opposed to hardenable stainless alloys like 440. 

To which I replied:

Well, the new Wilson Phoenix blades are advertised as having 420 stainless steel runners (https://www.johnwilsonskates.com/phoenix).  So they're slowly coming around.

But remember, many manufacturing steps are fine tuned for the specific composition of steel.  Wilson & MK have had their manufacturing lines setup for plain carbon steel for many, many decades.  Unless they see a whole lot of skaters abandoning them for stainless steel blades made by competitors, there's little financial incentive for them to change over.   As I've written before, I wish Japanese manufacturers would enter this market (look at their upheavals in the cutlery, camera, and auto industries, e.g.); but skate blades so far appears to be too small a market to interest them.

Note that financial considerations are driving much of these decisions.  As far as I know, only SkateScience, a relatively niche supplier in a relatively niche sport, exclusively uses stainless steel for all their blades (I tried to confirm their current offerings, but I couldn't connect to their website).  Jackson Ultima, Riedell Eclipse, and Paramount all include a mix of stainless steel and plain carbon steel models in their product portfolio.

In an interesting twist, Riedell now uses stainless steel blades in all their low-end kits (https://www.ice.riedellskates.com/Catalog/Casual-Series?categoryId=&filters=&sortby=1&page=1&pageSize=8&criteria=&view=list&columns=572b1e46-309a-4eaf-bb29-a43a00f436d43e9fe427-f6e9-4461-875b-a40300ff7c8a30d49142-2d5f-4e19-942d-a43a00f436cd).  But these low-end blades do not bear the "Eclipse" label.  And unlike the Eclipse blades, these low-end blades (a) are made in China instead of Canada, (b) are not sold as separate blades in US and Canada, and (c) do not have a specified grade of stainless steel.

* The grades of both plain carbon steel and stainless steel used in figure skate blades are magnetic.  I haven't a clue as to what "clean steel" is (steel from which dirt has been removed?  88) ).  [ETA:  By the way, the article you cited is wrong.  They claim stainless steel is magnetic because it contains chromium.  By industry definition of stainless steel, all stainless steels must contain a specified minimum percentage of chromium.  But some grades of stainless steel are non-magnetic.]
Title: Re: Rust removal from blades - experiments
Post by: Kaitsu on August 14, 2022, 02:15:24 PM
Can you explain in very simple terms the probable reason why MK and JW don't use stainless steel in most of their reasonably high end figure skating blades?

Stainless steel is more expensive and harder to be machined. https://evden.com/why-is-stainless-steel-hard-to-machine/

Shiny chrome is visually more pretty than matte stainless steel. This is the reason why quite many stainless steel blades does have stainless steel runners and aluminum frame. Most of the polished the stainless steel blades are pure grab. Polishing stainless steel to mirror finish rounds the edges and very often ruins datum's which are used to check edges evenness. So far I have not seen any polished stainless steel blades what I could consider to use. To clarify, I have never hold Skate Science blades on my hands.

General information related to steels.
https://casiberia.com/resource/steel-information/330

I do have all these three: The Pink Stuff, Bar Keepers Friend and Universal Stone. I will not start to measure how much they remove material, but I can do some other test if you can provide good ideas how to test them. Reason why I do not even try to measure how much they remove material is that it would require such a high measuring accuracy, that I cannot provide it. Measuring less than one micrometer changes is not realistic scenario even I could use very accurate measuring devices. Measuring uncertainly is so huge compared to the material removal rate that I can bet that none of us cannot measure enough accurately. To see some measurable wear, I should polish probably hours and for that I do not have any interest or motivation. Even I would polish several hours, how to ensure that I am doing everything 100% identically.

Most likely Universal Stone is most abrasive from these three. This claim is based purely to color of washing sponge after treatment.
Title: Re: Rust removal from blades - experiments
Post by: Query on August 14, 2022, 06:37:03 PM
I guess it also makes sense for blade makers to have products sold at a range of prices, with the most desirable properties only in the most expensive.

I'm not sure how thick good brand skate plating is.  I wouldn't have guessed that a few microns abrasion would matter - though I guess people who have to remove rust over and over could eventually abrade enough that way to matter.

So many different steels!